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#catalysis — Public Fediverse posts

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  1. #RobSelects preprint of the week #ChemRxiv: Phenoxythiazoline-supported cobalt-catalyzed cross-coupling of aryl bronic acids with alkyl halides promoted by triisopropyl borate. #catalysis doi.org/10.26434/chemrxiv.1500

  2. A synthetic enzyme mimic has been developed to catalyze the insertion of an oxygen atom into stable aromatic rings, driving chemical reactions that run entirely on oxygen and produce only water as waste. The artificial system successfully replicates the function of naturally occurring extradiol dioxygenase enzymes while utilizing a non-natural metal ion.
    #SyntheticChemistry #BiomimeticChemistry #GreenChemistry #Catalysis #sflorg
    sflorg.com/2026/08/chm08092601

  3. Congrats to Francis H. Arnold and Tao Zhang on receiving the Dr. Karl Wamsler #Innovation Award from TUM and Clariant for their outstanding achievements in #catalysis research, including biocatalysis and white #biotechnology: go.tum.de/549571 👏

    📷A. Heddergott

  4. 💬 Behind the Science Interview with Navadheer Yalamanchili (École Polytechnique Fédérale de Lausanne (EPFL), Switzerland)

    He discusses how the self-assembly of simple catalysts into a chiral environment enables efficient deracemization of racemic mixtures, avoiding the need to synthesize complex chiral catalysts

    chemistryviews.org/teaching-a-

    #EPFL #catalysis #organicchemistry

  5. #RobSelects preprint of the week #ChemRxiv: Nickel-catalyzed enantioselective cross-coupling of alpha-bromo amides with alkylzirconocenes under blue light irradiation #catalysis doi.org/10.26434/chemrxiv.1500

  6. How can we predict chemical reactions more accurately? Robert Mayer, our newly appointed Professor of Physical-Organic Chemistry of Catalysis, explores this question. Using automated experiments and data-driven models, he investigates catalytic reactions to identify optimal conditions for chemical syntheses more quickly. Learn more in the latest NewIn episode: go.tum.de/806519

    ▶️youtu.be/xE8o-HLqPV8

    #Catalysis #ChemicalResearch #OriginsofLife

    📹TUM ProLehre
    📷A. Heddergott

  7. A team led by chemist @[email protected] from the Institute of Organic Chemistry at the University of #Münster has developed a new light-driven triple #catalysis.

    Three-dimensional molecules th...

  8. Why does liquid hydrogen slowly disappear during storage?

    Residual ortho-hydrogen releases heat as it converts to the more stable para form.

    New catalysts accelerate this transition beforehand, helping limit costly boil-off losses.

    🔗 phys.org/news/2026-05-catalyst

    #Hydrogen #Cryogenics #EnergyStorage #Catalysis #science

  9. #RobSelects preprint of the week #ChemRxiv: Nickel(0)-olefin pincer-catalyzed hydrogenation of carbonyls under mild conditions. #catalysis doi.org/10.26434/chemrxiv.1500

  10. #RobSelects paper of the week #angew_chem: Chiral phosphine-ligated enantioselective palladium-catalyzed aminoarylation of protected ortho-allyl anilines with aryl bromides. #catalysis doi.org/10.1002/anie.8602143

  11. #RobSelects paper of the week #Chem: Copper-catalyzed enantioconvergent coupling of alkyl radicals with secondary phosphine oxides. #catalysis doi.org/10.1016/j.chempr.2026.

  12. #RobSelects paper of the week #NatureChemistry: Switchable copper-catalyzed N-alpha or N-beta arylation of 3-substituted pyrazoles via ligand choice #catalysis doi.org/10.1038/s41557-026-021

  13. #RobSelects paper of the week #J_A_C_S: Ortho-carbon-hydrogen-alyklation of bromoarenes catalyzed by an imidazole-olefin-ligated palladium complex. #catalysis doi.org/10.1021/jacs.6c02010

  14. #RobSelects paper of the week #OrgLett: Isothiourea-catalyzed enantioselective higher-order cycloaddition of photochemically generated ketenes with triflate-substituted tropolones. #catalysis doi.org/10.1021/acs.orglett.6c

  15. #RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis doi.org/10.1021/jacs.6c06343

  16. #RobSelects preprint of the week #ChemRxiv: Nickel-catalyzed Suzuki-Miyaura cross coupling of ketones with boronic esters via in-situ ketone derivatization. #catalysis doi.org/10.26434/chemrxiv.1500

  17. #RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis doi.org/10.1021/jacs.6c05065

  18. #RobSelects preprint of the week #ChemRxiv: Palladium-copper co-catalyzed carbenylative Buchwald-Hartwig coupling between aryl halides, N-tosylhydrazones, and anilines. #catalysis doi.org/10.26434/chemrxiv.1500

  19. #RobSelects preprint of the week #ChemRxiv: Stereoselective nickel metallaphotoredox-catalyzed carbon-carbon cross-coupling of alcohols with gem-dibromoalkenes. #catalysis doi.org/10.26434/chemrxiv.1500

  20. #RobSelects paper of the week ScienceMagazine: Diastereoselective silver-catalyzed carbon-hydrogen activation and carbon-nitrogen bond formation with chiral sulfonimidamide reactants. #catalysis doi.org/10.1126/science.aee3321

  21. #RobSelects paper of the week #NatureCatalysis: Atroposelective nucleophilic aromatic substitution of fluoronaphthalenes with phenols catalyzed by a chiral phosphonium salt. #catalysis doi.org/10.1038/s41929-026-015

  22. #RobSelects paper of the week #ScienceMagazine: Carbazole-substituted pyridine bis(oxazoline) complexes as a readily accessible family of potent chiral photocatalysts. #catalysis doi.org/10.1126/science.aeb5832

  23. #RobSelects preprint of the week #ChemRxiv: Methylbutyl boronate salt as methylation reagent in Suzuki-Miyaura cross couplings. #catalysis doi.org/10.26434/chemrxiv.1500

  24. Why can't we just reverse the Haber-Bosch process?

    In the latest episode, I talk to Prof. Malte Behrens @SolidStateChemCatal_Kiel about ammonia as a possible hydrogen carrier.

    We dive deep into the chemistry of ammonia cracking and explain why the classic iron catalyst loses its activity. Find out how alloying iron with cobalt might just be the solution to unlocking green energy transport via ammonia!

    Listen here: innovateandreact.com/why-rever

    #Chemistry #Catalysis #Ammonia

  25. #RobSelects paper of the week #J_A_C_S: Asymmetric Sm-catalyzed carbon-carbon coupling between alkenes and ketones forming tertiary alcohols. #catalysis doi.org/10.1021/jacs.5c20884