#j_a_c_s — Public Fediverse posts

#RobSelects paper of the week #J_A_C_S: 4-Dimethylaminopyridine-trapped hydroxycarbenes as nucleophiles reacting with aldehydes to form cross-benzoin products. #orgchem https://doi.org/10.1021/jacs.6c14714

#RobSelects paper of the week #J_A_C_S: 4-Dimethylaminopyridine-trapped hydroxycarbenes as nucleophiles reacting with aldehydes to form cross-benzoin products. #orgchem https://doi.org/10.1021/jacs.6c14714

#RobSelects paper of the week #J_A_C_S: 4-Dimethylaminopyridine-trapped hydroxycarbenes as nucleophiles reacting with aldehydes to form cross-benzoin products. #orgchem https://doi.org/10.1021/jacs.6c14714

#RobSelects paper of the week #J_A_C_S: 4-Dimethylaminopyridine-trapped hydroxycarbenes as nucleophiles reacting with aldehydes to form cross-benzoin products. #orgchem https://doi.org/10.1021/jacs.6c14714

#RobSelects paper of the week #J_A_C_S: 4-Dimethylaminopyridine-trapped hydroxycarbenes as nucleophiles reacting with aldehydes to form cross-benzoin products. #orgchem https://doi.org/10.1021/jacs.6c14714

#RobSelects paper of the week #J_A_C_S: Ortho-carbon-hydrogen-alyklation of bromoarenes catalyzed by an imidazole-olefin-ligated palladium complex. #catalysis https://doi.org/10.1021/jacs.6c02010

#RobSelects paper of the week #J_A_C_S: Ortho-carbon-hydrogen-alyklation of bromoarenes catalyzed by an imidazole-olefin-ligated palladium complex. #catalysis https://doi.org/10.1021/jacs.6c02010

#RobSelects paper of the week #J_A_C_S: Ortho-carbon-hydrogen-alyklation of bromoarenes catalyzed by an imidazole-olefin-ligated palladium complex. #catalysis https://doi.org/10.1021/jacs.6c02010

#RobSelects paper of the week #J_A_C_S: Ortho-carbon-hydrogen-alyklation of bromoarenes catalyzed by an imidazole-olefin-ligated palladium complex. #catalysis https://doi.org/10.1021/jacs.6c02010

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis https://doi.org/10.1021/jacs.6c05065

#RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis https://doi.org/10.1021/jacs.6c05065

#RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis https://doi.org/10.1021/jacs.6c05065

#RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis https://doi.org/10.1021/jacs.6c05065

#RobSelects paper of the week #J_A_C_S: Excited-state nucleophilic aromatic substitution of nitroarenes. #orgchem https://doi.org/10.1021/jacs.5c21841

#RobSelects paper of the week #J_A_C_S: Excited-state nucleophilic aromatic substitution of nitroarenes. #orgchem https://doi.org/10.1021/jacs.5c21841

#RobSelects paper of the week #J_A_C_S: Excited-state nucleophilic aromatic substitution of nitroarenes. #orgchem https://doi.org/10.1021/jacs.5c21841

#RobSelects paper of the week #J_A_C_S: Excited-state nucleophilic aromatic substitution of nitroarenes. #orgchem https://doi.org/10.1021/jacs.5c21841

#RobSelects paper of the week #J_A_C_S: Asymmetric Sm-catalyzed carbon-carbon coupling between alkenes and ketones forming tertiary alcohols. #catalysis https://doi.org/10.1021/jacs.5c20884

#RobSelects paper of the week #J_A_C_S: Asymmetric Sm-catalyzed carbon-carbon coupling between alkenes and ketones forming tertiary alcohols. #catalysis https://doi.org/10.1021/jacs.5c20884

#RobSelects paper of the week #J_A_C_S: Asymmetric Sm-catalyzed carbon-carbon coupling between alkenes and ketones forming tertiary alcohols. #catalysis https://doi.org/10.1021/jacs.5c20884

#RobSelects paper of the week #J_A_C_S: Asymmetric Sm-catalyzed carbon-carbon coupling between alkenes and ketones forming tertiary alcohols. #catalysis https://doi.org/10.1021/jacs.5c20884

#RobSelects paper of the week #J_A_C_S: Excited-state triplet thiazole-2-thione biradicals as radical covalent catalysts for skeletal reorganization of N-sulfonyl vinylaziridines. #catalysis https://doi.org/10.1021/jacs.5c20284

#RobSelects paper of the week #J_A_C_S: Excited-state triplet thiazole-2-thione biradicals as radical covalent catalysts for skeletal reorganization of N-sulfonyl vinylaziridines. #catalysis https://doi.org/10.1021/jacs.5c20284

#RobSelects paper of the week #J_A_C_S: Excited-state triplet thiazole-2-thione biradicals as radical covalent catalysts for skeletal reorganization of N-sulfonyl vinylaziridines. #catalysis https://doi.org/10.1021/jacs.5c20284

#RobSelects paper of the week #J_A_C_S: Excited-state triplet thiazole-2-thione biradicals as radical covalent catalysts for skeletal reorganization of N-sulfonyl vinylaziridines. #catalysis https://doi.org/10.1021/jacs.5c20284

#RobSelects paper of the week #J_A_C_S: Iridium-catalyzed reduction of beta-boryl amides triggers stereospecific cyclization to form aminocyclopropanes. #catalysis https://doi.org/10.1021/jacs.5c21144

#RobSelects paper of the week #J_A_C_S: Iridium-catalyzed reduction of beta-boryl amides triggers stereospecific cyclization to form aminocyclopropanes. #catalysis https://doi.org/10.1021/jacs.5c21144

#RobSelects paper of the week #J_A_C_S: Iridium-catalyzed reduction of beta-boryl amides triggers stereospecific cyclization to form aminocyclopropanes. #catalysis https://doi.org/10.1021/jacs.5c21144

#RobSelects paper of the week #J_A_C_S: Iridium-catalyzed reduction of beta-boryl amides triggers stereospecific cyclization to form aminocyclopropanes. #catalysis https://doi.org/10.1021/jacs.5c21144

#RobSelects paper of the week #J_A_C_S: Comprehensive investigation of regio- and stereoselectivity of iridium-catalyzed carbon-hydrogen borylation of small substituted aliphatic carbocycles. #catalysis https://doi.org/10.1021/jacs.5c18839

#RobSelects paper of the week #J_A_C_S: Comprehensive investigation of regio- and stereoselectivity of iridium-catalyzed carbon-hydrogen borylation of small substituted aliphatic carbocycles. #catalysis https://doi.org/10.1021/jacs.5c18839

#RobSelects paper of the week #J_A_C_S: Comprehensive investigation of regio- and stereoselectivity of iridium-catalyzed carbon-hydrogen borylation of small substituted aliphatic carbocycles. #catalysis https://doi.org/10.1021/jacs.5c18839

#RobSelects paper of the week #J_A_C_S: Comprehensive investigation of regio- and stereoselectivity of iridium-catalyzed carbon-hydrogen borylation of small substituted aliphatic carbocycles. #catalysis https://doi.org/10.1021/jacs.5c18839

#RobSelects paper of the week #J_A_C_S: Enantioselective cycloaddition of cyclopropanes across alkynes via diamine phosphine oxide-ligated nickel-aluminum bimetallic catalysts. #catalysis https://doi.org/10.1021/jacs.5c18087

#RobSelects paper of the week #J_A_C_S: Enantioselective cycloaddition of cyclopropanes across alkynes via diamine phosphine oxide-ligated nickel-aluminum bimetallic catalysts. #catalysis https://doi.org/10.1021/jacs.5c18087

#RobSelects paper of the week #J_A_C_S: Enantioselective cycloaddition of cyclopropanes across alkynes via diamine phosphine oxide-ligated nickel-aluminum bimetallic catalysts. #catalysis https://doi.org/10.1021/jacs.5c18087

#RobSelects paper of the week #J_A_C_S: Enantioselective cycloaddition of cyclopropanes across alkynes via diamine phosphine oxide-ligated nickel-aluminum bimetallic catalysts. #catalysis https://doi.org/10.1021/jacs.5c18087

#RobSelects paper of the week #J_A_C_S: Pd-Catalyzed Buchwald-Hartwig amination with a mild and solube potassium alkyl carboxylate salt and a phosphorinane ligand. #catalysis https://doi.org/10.1021/jacs.5c07790

#RobSelects paper of the week #J_A_C_S: Pd-Catalyzed Buchwald-Hartwig amination with a mild and solube potassium alkyl carboxylate salt and a phosphorinane ligand. #catalysis https://doi.org/10.1021/jacs.5c07790

#RobSelects paper of the week #J_A_C_S: Pd-Catalyzed Buchwald-Hartwig amination with a mild and solube potassium alkyl carboxylate salt and a phosphorinane ligand. #catalysis https://doi.org/10.1021/jacs.5c07790

#RobSelects paper of the week #J_A_C_S: Pd-Catalyzed Buchwald-Hartwig amination with a mild and solube potassium alkyl carboxylate salt and a phosphorinane ligand. #catalysis https://doi.org/10.1021/jacs.5c07790

#RobSelects paper of the week #J_A_C_S: Synthesis of substituted cycloheptatrienes through insertion of a chromium fluorocarbyne into the adduct of a nucleophile and benzene. #inorgchem https://doi.org/10.1021/jacs.5c16875

#RobSelects paper of the week #J_A_C_S: Synthesis of substituted cycloheptatrienes through insertion of a chromium fluorocarbyne into the adduct of a nucleophile and benzene. #inorgchem https://doi.org/10.1021/jacs.5c16875

#RobSelects paper of the week #J_A_C_S: Synthesis of substituted cycloheptatrienes through insertion of a chromium fluorocarbyne into the adduct of a nucleophile and benzene. #inorgchem https://doi.org/10.1021/jacs.5c16875

#RobSelects paper of the week #J_A_C_S: Synthesis of substituted cycloheptatrienes through insertion of a chromium fluorocarbyne into the adduct of a nucleophile and benzene. #inorgchem https://doi.org/10.1021/jacs.5c16875

#RobSelects paper of the week #J_A_C_S: Frustrated Lewis pair catalyst for coupling formate esters with vinyl and aryl organoboranes. #catalysis https://doi.org/10.1021/jacs.5c17878

#RobSelects paper of the week #J_A_C_S: Frustrated Lewis pair catalyst for coupling formate esters with vinyl and aryl organoboranes. #catalysis https://doi.org/10.1021/jacs.5c17878

#RobSelects paper of the week #J_A_C_S: Frustrated Lewis pair catalyst for coupling formate esters with vinyl and aryl organoboranes. #catalysis https://doi.org/10.1021/jacs.5c17878

#RobSelects paper of the week #J_A_C_S: Frustrated Lewis pair catalyst for coupling formate esters with vinyl and aryl organoboranes. #catalysis https://doi.org/10.1021/jacs.5c17878

#RobSelects paper of the week #J_A_C_S: Photochemical generation of carbon radicals from organoboron starting materials enabled via catalyst-borate complexes. #catalysis https://doi.org/10.1021/jacs.5c17266

#RobSelects paper of the week #J_A_C_S: Photochemical generation of carbon radicals from organoboron starting materials enabled via catalyst-borate complexes. #catalysis https://doi.org/10.1021/jacs.5c17266

#RobSelects paper of the week #J_A_C_S: Photochemical generation of carbon radicals from organoboron starting materials enabled via catalyst-borate complexes. #catalysis https://doi.org/10.1021/jacs.5c17266

#RobSelects paper of the week #J_A_C_S: Photochemical generation of carbon radicals from organoboron starting materials enabled via catalyst-borate complexes. #catalysis https://doi.org/10.1021/jacs.5c17266

#RobSelects paper of the week #J_A_C_S: Deriving a model for estimating rates of C-X reductive elimination from palladium(II) derived via causal inference. #catalysis https://doi.org/10.1021/jacs.5c06124

#RobSelects paper of the week #J_A_C_S: Deriving a model for estimating rates of C-X reductive elimination from palladium(II) derived via causal inference. #catalysis https://doi.org/10.1021/jacs.5c06124