#robselects — Public Fediverse posts

#RobSelects preprint of the week #ChemRxiv: Phenoxythiazoline-supported cobalt-catalyzed cross-coupling of aryl bronic acids with alkyl halides promoted by triisopropyl borate. #catalysis https://doi.org/10.26434/chemrxiv.15007381/v1

#RobSelects preprint of the week #ChemRxiv: Phenoxythiazoline-supported cobalt-catalyzed cross-coupling of aryl bronic acids with alkyl halides promoted by triisopropyl borate. #catalysis https://doi.org/10.26434/chemrxiv.15007381/v1

#RobSelects preprint of the week #ChemRxiv: Reformulating g-xTB in the overlapping subsystem-based divide-and-conquer approach. #compchem https://doi.org/10.26434/chemrxiv.15007156/v1

#RobSelects preprint of the week #ChemRxiv: Reformulating g-xTB in the overlapping subsystem-based divide-and-conquer approach. #compchem https://doi.org/10.26434/chemrxiv.15007156/v1

#RobSelects preprint of the week #ChemRxiv: Dithiophosphoric acids as organocatalysts for radical chemistry. #catalysis https://doi.org/10.26434/chemrxiv.15006758/v1

#RobSelects preprint of the week #ChemRxiv: Dithiophosphoric acids as organocatalysts for radical chemistry. #catalysis https://doi.org/10.26434/chemrxiv.15006758/v1

#RobSelects preprint of the week #ChemRxiv: Mitsunobu reaction via iminophosphoranes formed in situ from aryl azides and trialkyl phosphines. #orgchem https://doi.org/10.26434/chemrxiv.15006188/v2

#RobSelects preprint of the week #ChemRxiv: Mitsunobu reaction via iminophosphoranes formed in situ from aryl azides and trialkyl phosphines. #orgchem https://doi.org/10.26434/chemrxiv.15006188/v2

#RobSelects preprint of the week #ChemRxiv: Nickel-catalyzed enantioselective cross-coupling of alpha-bromo amides with alkylzirconocenes under blue light irradiation #catalysis https://doi.org/10.26434/chemrxiv.15005912/v1

#RobSelects preprint of the week #ChemRxiv: Nickel-catalyzed enantioselective cross-coupling of alpha-bromo amides with alkylzirconocenes under blue light irradiation #catalysis https://doi.org/10.26434/chemrxiv.15005912/v1

#RobSelects paper of the week #angew_chem: Deaminative alkynylation of aliphatic primary amines with alkynyl bromides. #orgchem https://doi.org/10.1002/anie.1809869

#RobSelects paper of the week #angew_chem: Deaminative alkynylation of aliphatic primary amines with alkynyl bromides. #orgchem https://doi.org/10.1002/anie.1809869

#RobSelects preprint of the week #ChemRxiv: Nickel(0)-olefin pincer-catalyzed hydrogenation of carbonyls under mild conditions. #catalysis https://doi.org/10.26434/chemrxiv.15005286/v1

#RobSelects preprint of the week #ChemRxiv: Nickel(0)-olefin pincer-catalyzed hydrogenation of carbonyls under mild conditions. #catalysis https://doi.org/10.26434/chemrxiv.15005286/v1

#RobSelects paper of the week #angew_chem: Chiral phosphine-ligated enantioselective palladium-catalyzed aminoarylation of protected ortho-allyl anilines with aryl bromides. #catalysis https://doi.org/10.1002/anie.8602143

#RobSelects preprint of the week #ChemRxiv: Telemetry enables continuous thermometric and calorimetric monitoring of chemical reactions. #autochem https://doi.org/10.26434/chemrxiv.15005162/v1

#RobSelects paper of the week #Chem: Copper-catalyzed enantioconvergent coupling of alkyl radicals with secondary phosphine oxides. #catalysis https://doi.org/10.1016/j.chempr.2026.103100

#RobSelects preprint of the week #ChemRxiv: Photocatalyzed sulfonylative Pauson-Khand type reaction on 1,6-enynes. #catalysis https://doi.org/10.26434/chemrxiv.15004788/v1

#RobSelects paper of the week #NatureChemistry: Switchable copper-catalyzed N-alpha or N-beta arylation of 3-substituted pyrazoles via ligand choice #catalysis https://doi.org/10.1038/s41557-026-02148-z

#RobSelects preprint of the week #ChemRxiv: A density functional approximation incorporating a multilayer perceptron having integrals of local descriptors as features. #theochem https://doi.org/10.26434/chemrxiv.15004450/v2

#RobSelects paper of the week #J_A_C_S: Ortho-carbon-hydrogen-alyklation of bromoarenes catalyzed by an imidazole-olefin-ligated palladium complex. #catalysis https://doi.org/10.1021/jacs.6c02010

#RobSelects preprint of the week #ChemRxiv: Multi-agent framework for planning and evaluating safety in chemistry and materials laboratories. #aichem https://doi.org/10.26434/chemrxiv.15004378/v1

#RobSelects paper of the week #OrgLett: Isothiourea-catalyzed enantioselective higher-order cycloaddition of photochemically generated ketenes with triflate-substituted tropolones. #catalysis https://doi.org/10.1021/acs.orglett.6c01642

#RobSelects paper of the week #OrgLett: Isothiourea-catalyzed enantioselective higher-order cycloaddition of photochemically generated ketenes with triflate-substituted tropolones. #catalysis https://doi.org/10.1021/acs.orglett.6c01642

#RobSelects preprint of the week #ChemRxiv: Reaction of iron carbenes with diazenes to form metallacyclobutanes that undergo subsequent cycloreversion. #orgmet https://doi.org/10.26434/chemrxiv-2025-10kzk/v2

#RobSelects preprint of the week #ChemRxiv: Reaction of iron carbenes with diazenes to form metallacyclobutanes that undergo subsequent cycloreversion. #orgmet https://doi.org/10.26434/chemrxiv-2025-10kzk/v2

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects paper of the week #J_A_C_S: Pincer-ligated cobalt-catalyzed four-component carbocarbonylation to form unsymmetric aliphatic ketones. #catalysis https://doi.org/10.1021/jacs.6c06343

#RobSelects preprint of the week #ChemRxiv: Nickel-catalyzed Suzuki-Miyaura cross coupling of ketones with boronic esters via in-situ ketone derivatization. #catalysis https://doi.org/10.26434/chemrxiv.15003005/v1

#RobSelects preprint of the week #ChemRxiv: Nickel-catalyzed Suzuki-Miyaura cross coupling of ketones with boronic esters via in-situ ketone derivatization. #catalysis https://doi.org/10.26434/chemrxiv.15003005/v1

#RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis https://doi.org/10.1021/jacs.6c05065

#RobSelects preprint of the week #ChemRxiv: Palladium-copper co-catalyzed carbenylative Buchwald-Hartwig coupling between aryl halides, N-tosylhydrazones, and anilines. #catalysis https://doi.org/10.26434/chemrxiv.15002705/v1

#RobSelects paper of the week #JCTC: Incorporating neural networks into the PBE functional for local density-dependent reparameterization of exchange and correlation terms. #aichem https://doi.org/10.1021/acs.jctc.6c00270

#RobSelects preprint of the week #ChemRxiv: Stereoselective nickel metallaphotoredox-catalyzed carbon-carbon cross-coupling of alcohols with gem-dibromoalkenes. #catalysis https://doi.org/10.26434/chemrxiv.15002635/v1

#RobSelects paper of the week ScienceMagazine: Diastereoselective silver-catalyzed carbon-hydrogen activation and carbon-nitrogen bond formation with chiral sulfonimidamide reactants. #catalysis https://doi.org/10.1126/science.aee3321

#RobSelects preprint of the week #ChemRxiv: Addition of hydroxylamines across cyclooctynes to form nitrones. #orgchem https://doi.org/10.26434/chemrxiv.15002347/v1

#RobSelects paper of the week #NatureCatalysis: Atroposelective nucleophilic aromatic substitution of fluoronaphthalenes with phenols catalyzed by a chiral phosphonium salt. #catalysis https://doi.org/10.1038/s41929-026-01522-x

#RobSelects preprint of the week #ChemRxiv: Integrating deep generative models into automated transition state discovery workflows. #aichem https://doi.org/10.26434/chemrxiv.15002135/v1

#RobSelects paper of the week #ScienceMagazine: Carbazole-substituted pyridine bis(oxazoline) complexes as a readily accessible family of potent chiral photocatalysts. #catalysis https://doi.org/10.1126/science.aeb5832

#RobSelects preprint of the week #ChemRxiv: Methylbutyl boronate salt as methylation reagent in Suzuki-Miyaura cross couplings. #catalysis https://doi.org/10.26434/chemrxiv.15001572/v1

#RobSelects paper of the week #J_A_C_S: Excited-state nucleophilic aromatic substitution of nitroarenes. #orgchem https://doi.org/10.1021/jacs.5c21841

#RobSelects paper of the week #ChemicalScience: Real-space analysis and visualization of steric repulsion based on the Pauli kinetic energy excess. #compchem https://doi.org/10.1039/D5SC07952G

#RobSelects preprint of the week #ChemRxiv: Nitrogen-nitrogen dehydrocoupling of iminoanilines via iron(III) chloride-catalyzed multi-site proton-coupled electron transfer. #catalyis https://doi.org/10.26434/chemrxiv-2025-vtv4x

#RobSelects paper of the week #JChemPhys: Automatically adapting minimal basis set parameters based on the local electronic environment #compchem https://doi.org/10.1063/5.0172373

#RobSelects paper of the week #J_A_C_S: Catalytic isomerization of cyclic ketones through carbonyl chain-walking. #catalysis https://doi.org/10.1021/jacs.3c05680

@robpollice Awesome to see that #RobSelects made it to Mastodon! #chemiverse

#RobSelects preprint of the week #ChemRxiv: Constructing a database of elementary reactions involving both breaking and forming two bonds in small organic molecules and their transition states. #compchem https://doi.org/10.26434/chemrxiv-2022-1vmwv