#robselects — Public Fediverse posts

#RobSelects paper of the week #J_A_C_S: Coupling between two tetrahedral carbon centers from an amine and a carboxylic acid catalyzed by an iron porphyrin forming quaternary carbons. #catalysis https://doi.org/10.1021/jacs.6c05065

#RobSelects preprint of the week #ChemRxiv: Palladium-copper co-catalyzed carbenylative Buchwald-Hartwig coupling between aryl halides, N-tosylhydrazones, and anilines. #catalysis https://doi.org/10.26434/chemrxiv.15002705/v1

#RobSelects preprint of the week #ChemRxiv: Stereoselective nickel metallaphotoredox-catalyzed carbon-carbon cross-coupling of alcohols with gem-dibromoalkenes. #catalysis https://doi.org/10.26434/chemrxiv.15002635/v1

#RobSelects paper of the week ScienceMagazine: Diastereoselective silver-catalyzed carbon-hydrogen activation and carbon-nitrogen bond formation with chiral sulfonimidamide reactants. #catalysis https://doi.org/10.1126/science.aee3321

#RobSelects preprint of the week #ChemRxiv: Addition of hydroxylamines across cyclooctynes to form nitrones. #orgchem https://doi.org/10.26434/chemrxiv.15002347/v1

#RobSelects paper of the week #NatureCatalysis: Atroposelective nucleophilic aromatic substitution of fluoronaphthalenes with phenols catalyzed by a chiral phosphonium salt. #catalysis https://doi.org/10.1038/s41929-026-01522-x

#RobSelects paper of the week #ScienceMagazine: Carbazole-substituted pyridine bis(oxazoline) complexes as a readily accessible family of potent chiral photocatalysts. #catalysis https://doi.org/10.1126/science.aeb5832

#RobSelects preprint of the week #ChemRxiv: Methylbutyl boronate salt as methylation reagent in Suzuki-Miyaura cross couplings. #catalysis https://doi.org/10.26434/chemrxiv.15001572/v1

#RobSelects paper of the week #J_A_C_S: Excited-state nucleophilic aromatic substitution of nitroarenes. #orgchem https://doi.org/10.1021/jacs.5c21841

#RobSelects paper of the week J_A_C_S: Discovering approximate non-iterative algorithms for matrix-based electronic structure calculations via symbolic regression. #compchem https://doi.org/10.1021/jacs.5c22323

#RobSelects paper of the week J_A_C_S: Discovering approximate non-iterative algorithms for matrix-based electronic structure calculations via symbolic regression. #compchem https://doi.org/10.1021/jacs.5c22323

#RobSelects paper of the week #J_A_C_S: Asymmetric Sm-catalyzed carbon-carbon coupling between alkenes and ketones forming tertiary alcohols. #catalysis https://doi.org/10.1021/jacs.5c20884

#RobSelects paper of the week #ScienceMagazine: Intramolecular peptide-catalyst-controlled stereoselective Michael addition between the enamine of an aldehyde and a ketovinylester. #catalysis https://doi.org/10.1126/science.aec8992

#RobSelects paper of the week #ChemicalScience: Electrochemical one-pot method for rhodium(II)-catalyzed cyclopropanation via in situ oxidation of tert-butyl hydrazones to diazo compounds. #catalysis https://doi.org/10.1039/D5SC08940A

#RobSelects paper of the week #ACSCentSci: Systematic statistical analysis of 66,000 organic reactions from high-throughput experiments representative of pharmaceutical drug discovery. #orgchem https://doi.org/10.1021/acscentsci.5c02031

#RobSelects paper of the week #J_A_C_S: Excited-state triplet thiazole-2-thione biradicals as radical covalent catalysts for skeletal reorganization of N-sulfonyl vinylaziridines. #catalysis https://doi.org/10.1021/jacs.5c20284

#RobSelects paper of the week #J_A_C_S: Iridium-catalyzed reduction of beta-boryl amides triggers stereospecific cyclization to form aminocyclopropanes. #catalysis https://doi.org/10.1021/jacs.5c21144

#RobSelects paper of the week #ACSCatalysis: Nickel-catalyzed dehydroxylative cross-coupling of 1-substituted cyclopropanols and boronic acids via gamma-carbon-carbon activation. #catalysis https://doi.org/10.1021/acscatal.5c07422

#RobSelects preprint of the week #ChemRxiv: Photochemical conversion of aryl azides into pyridines via triplet aryl nitrenes. #orgchem https://doi.org/10.26434/chemrxiv-2026-jn9zb

#RobSelects preprint of the week #ChemRxiv: Photochemical isomerization of N-substituted pyrazoles to imidazoles. #orgchem https://doi.org/10.26434/chemrxiv-2026-68vcj

#RobSelects paper of the week #J_A_C_S: Comprehensive investigation of regio- and stereoselectivity of iridium-catalyzed carbon-hydrogen borylation of small substituted aliphatic carbocycles. #catalysis https://doi.org/10.1021/jacs.5c18839

#RobSelects preprint of the week #ChemRxiv: Designing a hemilabile bisphosphine ligand for sterically hindered nickel-catalyzed Suzuki-Miyaura cross couplings. #catalysis https://doi.org/10.26434/chemrxiv-2025-q7td5

#RobSelects preprint of the week #ChemRxiv: Utilizing simulated descriptors from catalytically relevant structures for enantioselectivity prediction and optimization. #catalysis https://doi.org/10.26434/chemrxiv-2025-f5ddv-v2

#RobSelects preprint of the week #ChemRxiv: Intermolecular alkene hydroamination promoted by single electron reduction. #orgchem https://doi.org/10.26434/chemrxiv-2025-fblsl

#RobSelects preprint of the week #ChemRxiv: E-Selective hydrazine-mediated cross carbonyl-olefine metathesis. #orgchem https://doi.org/10.26434/chemrxiv-2025-hb5l1

#RobSelects preprint of the week #ChemRxiv: Comprehensive mechanistic study of the oxidative aminative cleavage of alkenes with a hypervalent iodine oxidant and ammonium carbamate. #orgchem https://doi.org/10.26434/chemrxiv-2025-6cdgb

#RobSelects paper of the week #J_A_C_S: Reversible carbon-hydrogen activation of benzene and unactivated arenes with a nickel(0)-silylene complex. #orgchem https://doi.org/10.1021/jacs.5c10922

#RobSelects paper of the week #J_A_C_S: Leveraging a [1,3]-hydride shift in alpha-fluoro-diborylalkanes to synthesize cyclopropyl boronic esters. #orgchem https://doi.org/10.1021/jacs.5c08276

#RobSelects paper of the week #angew_chem: Generation and characterization of a triphenylphosphine-stabilized monovalent carbon atom with a triplet ground state. #orgchem https://doi.org/10.1002/anie.202424166

#RobSelects paper of the week #ChemSci: Design of molecules showing reduced charge recombination rates of photogenerated charge-separated states upon temperature increase. #physorg https://doi.org/10.1039/D3SC03609J