#angew_chem — Public Fediverse posts

#RobSelects paper of the week #angew_chem: Mapping the reactivities of 7-electron-4-center neutral radicals via quantum chemistry and data science. #inorgchem https://doi.org/10.1002/anie.202511509

#RobSelects paper of the week #angew_chem: Automated procedure for palladium-catalyzed iterative carbon-nitrogen and carbon-carbon cross coupling. #catalysis https://doi.org/10.1002/anie.202509974

#RobSelects paper of the week #angew_chem: Base mediated nucleophilic germylation of carbon-carbon double and triple bonds to form carbon-germanium bonds. #inorgchem https://doi.org/10.1002/anie.202506106

#RobSelects paper of the week #angew_chem: Highly enantioselective Mukaiyama aldol reaction catalyzed by a chiral bidentate iodine(I)-based halogen bond donor catalyst. #catalysis https://doi.org/10.1002/anie.202506476

#RobSelects paper of the week #angew_chem: Probing electrostatic interactions in nucleophilic substitutions through rotation rates in molecular motors with analogous structures. #physorg https://doi.org/10.1002/anie.202505483

#RobSelects paper of the week #angew_chem: Probing electrostatic interactions in nucleophilic substitutions through rotation rates in molecular motors with analogous structures. #physorg https://doi.org/10.1002/anie.202505483

#RobSelects paper of the week #angew_chem: Probing electrostatic interactions in nucleophilic substitutions through rotation rates in molecular motors with analogous structures. #physorg https://doi.org/10.1002/anie.202505483

#RobSelects paper of the week #angew_chem: Probing electrostatic interactions in nucleophilic substitutions through rotation rates in molecular motors with analogous structures. #physorg https://doi.org/10.1002/anie.202505483

#RobSelects paper of the week #angew_chem: A global optimization and structure sampling algorithm that does not rely on molecular dynamics. #compchem https://doi.org/10.1002/anie.202500393

#RobSelects paper of the week #angew_chem: Generation and characterization of a triphenylphosphine-stabilized monovalent carbon atom with a triplet ground state. #orgchem https://doi.org/10.1002/anie.202424166

#RobSelects paper of the week #angew_chem: Azide-Wittig reaction between azides and aldehydes forming triazabutadienes enabled by phosphines #orgchem https://doi.org/10.1002/anie.202412982

#RobSelects paper of the week #angew_chem: Reaction of adamantylsilene with aldehydes or ketones forming alkenes via 1,2-silaoxetanes under neutral conditions. #orgchem https://doi.org/10.1002/anie.202411265

#Robselects paper of the week #angew_chem: Formal cycloaddition of Boc-protected 3-acylazetidines and alkenes through boron-centered radical catalysis. #catalysis https://doi.org/10.1002/anie.202406612

#RobSelects paper of the week #angew_chem: Machine learning-guided literature-based ligand selection for magnesium-catalyzed reactions. #aichem https://doi.org/10.1002/anie.202318487

#RobSelects paper of the week #angew_chem: Non-directed manganese-catalyzed carbon-hydrogen hydroxylation of tert-butyl groups with hydrogen peroxide. #catalysis https://doi.org/10.1002/anie.202402858

#RobSelects paper of the week #angew_chem: Stereoselective synthesis of azabicycles enabled by complementary Lewis acids via inverse hydride shuttle catalysis. #catalysis https://doi.org/10.1002/anie.202320001

Behind the Science Interview: Singlet Fission in a New Series of Tetracene Oligomers

Novel molecular system with a hexaphenylbenzene core and multiple tetracene chromophores arranged to dictate through-space coupling, addressing low singlet fission efficiencies in tetracene dimers

https://www.chemistryviews.org/behind-the-science-singlet-fission-in-a-new-series-of-tetracene-oligomers/

#chemistry #chemistryviews #chemviews #chemiverse #angew_chem #SingletFission #tetrcene #research

#RobSelects paper of the week #angew_chem: Studying carbon-hydrogen activation of methane catalyzed by a trispyrazolyl silver(I) complex in a micellar medium by all-atom molecular dynamics simulations. #compchem https://doi.org/10.1002/anie.202314773

#RobSelects paper of the week #angew_chem: Reductive cross-coupling of vinyl thianthrenium salt and secondary alkyl iodides via alkyl zinc by palladium catalysis #catalysis https://doi.org/10.1002/anie.202313659

A 2-Center-3-Electron π-Bond without a Supporting σ-Bond:
First Si- and P-containing analog of a bicyclo[1.1.0]butane radical anion shows unusual bonding motif

https://www.chemistryviews.org/a-2-center-3-electron-%cf%80-bond-without-a-supporting-%cf%83-bond/

#chemistry #chemistryviews #chemviews #chemiverse #research #angew_chem #InorganicChemistry

#RobSelects paper of the week #angew_chem: Using static polarizability to track bond breaking. #compchem https://doi.org/10.1002/anie.202312078

#RobSelects paper of the week #angew_chem: Improving catalytic activity of a rhodium(I) pincer complex by addition of coronene as a supramolecular binder. #catalysis https://doi.org/10.1002/anie.202307198

#RobSelects paper of the week #angew_chem: Introducing substrate-anion halogen bonding and substrate-catalyst halogen-halogen interactions for anion-binding catalysts effecting high levels of chiral induction. #catalysis https://doi.org/10.1002/anie.202304781

#RobSelects paper of the week #angew_chem: Hydrogen bonding-mediated insertion of fluorinated alkenes into activated alkyl fluorides. #orgchem https://doi.org/10.1002/anie.202302860

#RobSelects paper of the week #angew_chem: Diastereoselective cyclopropanation of alkenes with methylene pronucleophiles via electrolytically generated dicationic thianthrene-alkene adducts. #orgchem https://doi.org/10.1002/anie.202303032

#RobSelects paper of the week #angew_chem: Combined computational and experimental study of enantioselective helix inversion of [5]helicene catalyzed by the cavity of a chiral perylene bisimide cyclophane. #catalysis https://doi.org/10.1002/anie.202301301

#RobSelects paper of the week #angew_chem: Combining a genetic algorithm with reaction simulation to design improved catalysts for a Morita-Baylis-Hillman reaction. #catalysis https://doi.org/10.1002/anie.202218565

#RobSelects paper of the week #angew_chem: Automated screening of interaction sites between two fragments using a grid-based pre-screening and independent pocket, stack and angular searches. #compchem https://doi.org/10.1002/anie.202214477