#inorgchem — Public Fediverse posts

#RobSelects paper of the week #J_A_C_S: Synthesis of substituted cycloheptatrienes through insertion of a chromium fluorocarbyne into the adduct of a nucleophile and benzene. #inorgchem https://doi.org/10.1021/jacs.5c16875

#RobSelects paper of the week #angew_chem: Mapping the reactivities of 7-electron-4-center neutral radicals via quantum chemistry and data science. #inorgchem https://doi.org/10.1002/anie.202511509

#RobSelects paper of the week #angew_chem: Base mediated nucleophilic germylation of carbon-carbon double and triple bonds to form carbon-germanium bonds. #inorgchem https://doi.org/10.1002/anie.202506106

#RobSelects paper of the week #J_A_C_S: Reductive carbon dioxide activation by a dinuclear iron-aluminum complex. #inorgchem https://doi.org/10.1021/jacs.5c00944

#RobSelects preprint of the week #ChemRixv: Synthesis and reactivity of hexaphenyl-1,2-diphosphonium dication. #inorgchem https://doi.org/10.26434/chemrxiv-2025-xt8vg

Electron Delocalization across a Carborane Bridge

Monoanionic cluster shows unprecedented communication between the boron centers of opposing substituents

https://www.chemistryviews.org/electron-delocalization-across-a-carborane-bridge/

#delocalization #carboranes #inorgchem #inorganicchemistry #chemistry #chemistryviews

Phosphanyl Phosphagermene Synthesized

New compound reacts with CO₂ and nitriles like a frustrated Lewis pair and with amines and metal complexes via 1,2-addition reactions

https://www.chemistryviews.org/phosphanyl-phosphagermene-synthesized/

#smallmoleculeactivation #maingroupchemistry #inorgchem #inorganicchemistry #chemistry #chemistryviews

A Unique Complex with a Mg–Be Bond

Formal Mg(II)–Be(0) complex with a significantly polarized bond

https://chemistryviews.org/a-unique-complex-with-a-mg-be-bond/

#chemistry #chemistryviews #berylliumchemistry #lowvalent #inorganicchemistry #inorgchem

#RobSelects preprint of the week #ChemRxiv: Ligand exchange on an iron-aluminium heterobimetallic complex via type I dyotropic rearrangement. #inorgchem https://doi.org/10.26434/chemrxiv-2024-7vlzq

I was super happy after purchasing Pfennig's fancy #InorgChem book and was quite surprised to receive it today. It took less than a week for FedEx to bring it from the USA to Brazil.
The funny part is that #Wiley decided to give me someone else's engineering book and someone will receive MY book.

#RobSelects paper of the week #J_A_C_S: Comprehensive characterization of a complex with a vanadium-aluminium bond. #inorgchem https://doi.org/10.1021/jacs.3c13418

📢 New publication alert! "Rapid and Accurate Prediction of Axial Magnetic Anisotropy in Co(II) Complexes Using Machine Learning" now in Inorg. Chem. 🧪

https://doi.org/10.1021/acs.inorgchem.3c02569

#InorgChem #MachineLearning #MolecularMagnetism #compchem

📢 New publication alert! "Rapid and Accurate Prediction of Axial Magnetic Anisotropy in Co(II) Complexes Using Machine Learning" now in Inorg. Chem. 🧪
🔗 https://doi.org/10.1021/acs.inorgchem.3c02569
#InorgChem #MachineLearning #MolecularMagnetism

📢 New publication alert! "Rapid and Accurate Prediction of Axial Magnetic Anisotropy in Co(II) Complexes Using Machine Learning" now in Inorg. Chem. 🧪
🔗 https://doi.org/10.1021/acs.inorgchem.3c02569
#InorgChem #MachineLearning #MolecularMagnetism #compchem

📢 New publication alert! "Rapid and Accurate Prediction of Axial Magnetic Anisotropy in Co(II) Complexes Using Machine Learning" now in Inorg. Chem. 🧪
🔗 https://doi.org/10.1021/acs.inorgchem.3c02569
#InorgChem #MachineLearning #MolecularMagnetism #compchem