#jacs — Public Fediverse posts
Live and recent posts from across the Fediverse tagged #jacs, aggregated by home.social.
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Organocatalytic beta-glycosylation via SN1 type oxocarbenium: Benjamin List and coworkers from MPI developed a method to synthesize beta linked sugars from the trichloroacetimidate precursor by deploying a chiral acidic imidodiphosphorimidate catalyst. This work has been published in JACS 2025.
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Organocatalytic beta-glycosylation via SN1 type oxocarbenium: Benjamin List and coworkers from MPI developed a method to synthesize beta linked sugars from the trichloroacetimidate precursor by deploying a chiral acidic imidodiphosphorimidate catalyst. This work has been published in JACS 2025.
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Organocatalytic beta-glycosylation via SN1 type oxocarbenium: Benjamin List and coworkers from MPI developed a method to synthesize beta linked sugars from the trichloroacetimidate precursor by deploying a chiral acidic imidodiphosphorimidate catalyst. This work has been published in JACS 2025.
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Organocatalytic beta-glycosylation via SN1 type oxocarbenium: Benjamin List and coworkers from MPI developed a method to synthesize beta linked sugars from the trichloroacetimidate precursor by deploying a chiral acidic imidodiphosphorimidate catalyst. This work has been published in JACS 2025.
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Organocatalytic beta-glycosylation via SN1 type oxocarbenium: Benjamin List and coworkers from MPI developed a method to synthesize beta linked sugars from the trichloroacetimidate precursor by deploying a chiral acidic imidodiphosphorimidate catalyst. This work has been published in JACS 2025.
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https://www.europesays.com/ie/304781/ ACS150 JACS Symposium kicks off in Zurich #$150 #AcsNews #american #Chemical #Éire #Health #IE #Ireland #JACS #journal #series #SOCIETY #Switzerland #symposium #Zurich
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Fantastic paper from Brooks Able at Berkeley using an organic catalyst to achieve high molecular weight for poly(THF) via cationic ring-opening polymerization. The low ceiling temperatures of these polymers make them attractive targets for reversible polymerizations, but it has previously been really hard to get to the molecular weights required for good mechanical properties. #chemistry #polymers #JACS https://pubs.acs.org/doi/10.1021/jacs.5c18359
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Fantastic paper from Brooks Able at Berkeley using an organic catalyst to achieve high molecular weight for poly(THF) via cationic ring-opening polymerization. The low ceiling temperatures of these polymers make them attractive targets for reversible polymerizations, but it has previously been really hard to get to the molecular weights required for good mechanical properties. #chemistry #polymers #JACS https://pubs.acs.org/doi/10.1021/jacs.5c18359
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Fantastic paper from Brooks Able at Berkeley using an organic catalyst to achieve high molecular weight for poly(THF) via cationic ring-opening polymerization. The low ceiling temperatures of these polymers make them attractive targets for reversible polymerizations, but it has previously been really hard to get to the molecular weights required for good mechanical properties. #chemistry #polymers #JACS https://pubs.acs.org/doi/10.1021/jacs.5c18359
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Fantastic paper from Brooks Able at Berkeley using an organic catalyst to achieve high molecular weight for poly(THF) via cationic ring-opening polymerization. The low ceiling temperatures of these polymers make them attractive targets for reversible polymerizations, but it has previously been really hard to get to the molecular weights required for good mechanical properties. #chemistry #polymers #JACS https://pubs.acs.org/doi/10.1021/jacs.5c18359
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Fantastic paper from Brooks Able at Berkeley using an organic catalyst to achieve high molecular weight for poly(THF) via cationic ring-opening polymerization. The low ceiling temperatures of these polymers make them attractive targets for reversible polymerizations, but it has previously been really hard to get to the molecular weights required for good mechanical properties. #chemistry #polymers #JACS https://pubs.acs.org/doi/10.1021/jacs.5c18359
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A novel bifunctional molecule induces selective nitrosation of BTK. Mechanistically, it first covalent bind to BTK and the release NO, which yielded in the nitrosation of a cysteine side chain. Published in #JACS by Jiangbing Wu, Zhangjian Huang and coworkers (#China)
Read more on doi: 10.1021/jacs.5c07409 or on my page: https://me.organicchemistry.eu/post/nitrosation-jacs-2025/
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A novel bifunctional molecule induces selective nitrosation of BTK. Mechanistically, it first covalent bind to BTK and the release NO, which yielded in the nitrosation of a cysteine side chain. Published in #JACS by Jiangbing Wu, Zhangjian Huang and coworkers (#China)
Read more on doi: 10.1021/jacs.5c07409 or on my page: https://me.organicchemistry.eu/post/nitrosation-jacs-2025/
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A novel bifunctional molecule induces selective nitrosation of BTK. Mechanistically, it first covalent bind to BTK and the release NO, which yielded in the nitrosation of a cysteine side chain. Published in #JACS by Jiangbing Wu, Zhangjian Huang and coworkers (#China)
Read more on doi: 10.1021/jacs.5c07409 or on my page: https://me.organicchemistry.eu/post/nitrosation-jacs-2025/
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A novel bifunctional molecule induces selective nitrosation of BTK. Mechanistically, it first covalent bind to BTK and the release NO, which yielded in the nitrosation of a cysteine side chain. Published in #JACS by Jiangbing Wu, Zhangjian Huang and coworkers (#China)
Read more on doi: 10.1021/jacs.5c07409 or on my page: https://me.organicchemistry.eu/post/nitrosation-jacs-2025/
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A novel bifunctional molecule induces selective nitrosation of BTK. Mechanistically, it first covalent bind to BTK and the release NO, which yielded in the nitrosation of a cysteine side chain. Published in #JACS by Jiangbing Wu, Zhangjian Huang and coworkers (#China)
Read more on doi: 10.1021/jacs.5c07409 or on my page: https://me.organicchemistry.eu/post/nitrosation-jacs-2025/
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When you think of a reaction between an acid and an alcohol, you think of an ester as the product. MacMillan and co-workers from Princeton have now described a different pathway: Selective decarbonylative C-C coupling via a metal-catalyzed photoredox reaction. Read more about this in JACS:
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When you think of a reaction between an acid and an alcohol, you think of an ester as the product. MacMillan and co-workers from Princeton have now described a different pathway: Selective decarbonylative C-C coupling via a metal-catalyzed photoredox reaction. Read more about this in JACS:
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When you think of a reaction between an acid and an alcohol, you think of an ester as the product. MacMillan and co-workers from Princeton have now described a different pathway: Selective decarbonylative C-C coupling via a metal-catalyzed photoredox reaction. Read more about this in JACS:
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When you think of a reaction between an acid and an alcohol, you think of an ester as the product. MacMillan and co-workers from Princeton have now described a different pathway: Selective decarbonylative C-C coupling via a metal-catalyzed photoredox reaction. Read more about this in JACS:
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When you think of a reaction between an acid and an alcohol, you think of an ester as the product. MacMillan and co-workers from Princeton have now described a different pathway: Selective decarbonylative C-C coupling via a metal-catalyzed photoredox reaction. Read more about this in JACS:
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Novel enantioselective #synthesis of rubriflordilactone B by Gui and colleagues from the Chinese Academy of Science published in #JACS
This is already the second total synthesis of this group, with an interesting reaction cascade as the key reaction in this process. -
Novel enantioselective #synthesis of rubriflordilactone B by Gui and colleagues from the Chinese Academy of Science published in #JACS
This is already the second total synthesis of this group, with an interesting reaction cascade as the key reaction in this process. -
Novel enantioselective #synthesis of rubriflordilactone B by Gui and colleagues from the Chinese Academy of Science published in #JACS
This is already the second total synthesis of this group, with an interesting reaction cascade as the key reaction in this process. -
Novel enantioselective #synthesis of rubriflordilactone B by Gui and colleagues from the Chinese Academy of Science published in #JACS
This is already the second total synthesis of this group, with an interesting reaction cascade as the key reaction in this process. -
Novel enantioselective #synthesis of rubriflordilactone B by Gui and colleagues from the Chinese Academy of Science published in #JACS
This is already the second total synthesis of this group, with an interesting reaction cascade as the key reaction in this process. -
Luo et al. from Tsinghua University (#China) report in #JACS a novel method to create enantioenriched α-amino aldehydes using a chiral amine catalyst and iridium photocatalysis. Through this strategy α-amino aldehydes with up to 93% ee could be synthesised and subsequently stabilised via analogues formation (e.g. through Wittig reaction).
https://me.organicchemistry.eu/post/deracemization-aldehyde-jacs-2025/
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Luo et al. from Tsinghua University (#China) report in #JACS a novel method to create enantioenriched α-amino aldehydes using a chiral amine catalyst and iridium photocatalysis. Through this strategy α-amino aldehydes with up to 93% ee could be synthesised and subsequently stabilised via analogues formation (e.g. through Wittig reaction).
https://me.organicchemistry.eu/post/deracemization-aldehyde-jacs-2025/
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Luo et al. from Tsinghua University (#China) report in #JACS a novel method to create enantioenriched α-amino aldehydes using a chiral amine catalyst and iridium photocatalysis. Through this strategy α-amino aldehydes with up to 93% ee could be synthesised and subsequently stabilised via analogues formation (e.g. through Wittig reaction).
https://me.organicchemistry.eu/post/deracemization-aldehyde-jacs-2025/
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Luo et al. from Tsinghua University (#China) report in #JACS a novel method to create enantioenriched α-amino aldehydes using a chiral amine catalyst and iridium photocatalysis. Through this strategy α-amino aldehydes with up to 93% ee could be synthesised and subsequently stabilised via analogues formation (e.g. through Wittig reaction).
https://me.organicchemistry.eu/post/deracemization-aldehyde-jacs-2025/
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Luo et al. from Tsinghua University (#China) report in #JACS a novel method to create enantioenriched α-amino aldehydes using a chiral amine catalyst and iridium photocatalysis. Through this strategy α-amino aldehydes with up to 93% ee could be synthesised and subsequently stabilised via analogues formation (e.g. through Wittig reaction).
https://me.organicchemistry.eu/post/deracemization-aldehyde-jacs-2025/
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Joseph Tuccinardi and John Wood from Baylor University (#USA), introduced a novel strategy to efficiently synthesize the core scaffold of aleutianamine. Their study involved a vinylogous Mukaiyama-Michael reaction cascade using two previously unknown coupling partners. Published in #JACS
https://me.organicchemistry.eu/post/aleutianamine-jacs-2025/
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Joseph Tuccinardi and John Wood from Baylor University (#USA), introduced a novel strategy to efficiently synthesize the core scaffold of aleutianamine. Their study involved a vinylogous Mukaiyama-Michael reaction cascade using two previously unknown coupling partners. Published in #JACS
https://me.organicchemistry.eu/post/aleutianamine-jacs-2025/
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Joseph Tuccinardi and John Wood from Baylor University (#USA), introduced a novel strategy to efficiently synthesize the core scaffold of aleutianamine. Their study involved a vinylogous Mukaiyama-Michael reaction cascade using two previously unknown coupling partners. Published in #JACS
https://me.organicchemistry.eu/post/aleutianamine-jacs-2025/
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Joseph Tuccinardi and John Wood from Baylor University (#USA), introduced a novel strategy to efficiently synthesize the core scaffold of aleutianamine. Their study involved a vinylogous Mukaiyama-Michael reaction cascade using two previously unknown coupling partners. Published in #JACS
https://me.organicchemistry.eu/post/aleutianamine-jacs-2025/
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Joseph Tuccinardi and John Wood from Baylor University (#USA), introduced a novel strategy to efficiently synthesize the core scaffold of aleutianamine. Their study involved a vinylogous Mukaiyama-Michael reaction cascade using two previously unknown coupling partners. Published in #JACS
https://me.organicchemistry.eu/post/aleutianamine-jacs-2025/
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Another total synthesis in the spotlight: Already early this year Mingji Dai and his research team described the total synthesis of heilonine in #JACS (doi: 10.1021/jacs.3c13492). This synthesis is short and elegant, using multiple C-H functionalisations and a Nazarov cyclisation for their key step.
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Another total synthesis in the spotlight: Already early this year Mingji Dai and his research team described the total synthesis of heilonine in #JACS (doi: 10.1021/jacs.3c13492). This synthesis is short and elegant, using multiple C-H functionalisations and a Nazarov cyclisation for their key step.
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Another total synthesis in the spotlight: Already early this year Mingji Dai and his research team described the total synthesis of heilonine in #JACS (doi: 10.1021/jacs.3c13492). This synthesis is short and elegant, using multiple C-H functionalisations and a Nazarov cyclisation for their key step.
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Another total synthesis in the spotlight: Already early this year Mingji Dai and his research team described the total synthesis of heilonine in #JACS (doi: 10.1021/jacs.3c13492). This synthesis is short and elegant, using multiple C-H functionalisations and a Nazarov cyclisation for their key step.
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Another total synthesis in the spotlight: Already early this year Mingji Dai and his research team described the total synthesis of heilonine in #JACS (doi: 10.1021/jacs.3c13492). This synthesis is short and elegant, using multiple C-H functionalisations and a Nazarov cyclisation for their key step.
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Finaalllyyyy.... The first 𝐉𝐀𝐂𝐒 (IF - 14.5)😍🤩...
Special thanks to Felipe Fantuzzi (need any introduction? 3rd paper together🫂) & Holger group (University of Würzburg), Sougata Sarkar Sir (without whom I'd not even have an M.Sc.🙏)... & my mother (for insisting on asking Felipe to start a collaboration)😘😍
Link - https://pubs.acs.org/doi/10.1021/jacs.4c10967
#ACS #jacs #organometallic #computational #collaboration #journal #article #openaccess
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Efficient Synthesis of ProTide antivirals: A team from from #Fudan University and #Shanghai Jiao Tong University reporting a copper-catalyzed method for synthesizing chiral phosphates in #JACS.
This research represents a new tool for the synthesis of ProTide nucleoside analogues, providing an efficient route that can enhance the development of antiviral drugs in future studies.
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Efficient Synthesis of ProTide antivirals: A team from from #Fudan University and #Shanghai Jiao Tong University reporting a copper-catalyzed method for synthesizing chiral phosphates in #JACS.
This research represents a new tool for the synthesis of ProTide nucleoside analogues, providing an efficient route that can enhance the development of antiviral drugs in future studies.
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Efficient Synthesis of ProTide antivirals: A team from from #Fudan University and #Shanghai Jiao Tong University reporting a copper-catalyzed method for synthesizing chiral phosphates in #JACS.
This research represents a new tool for the synthesis of ProTide nucleoside analogues, providing an efficient route that can enhance the development of antiviral drugs in future studies.
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Efficient Synthesis of ProTide antivirals: A team from from #Fudan University and #Shanghai Jiao Tong University reporting a copper-catalyzed method for synthesizing chiral phosphates in #JACS.
This research represents a new tool for the synthesis of ProTide nucleoside analogues, providing an efficient route that can enhance the development of antiviral drugs in future studies.
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Efficient Synthesis of ProTide antivirals: A team from from #Fudan University and #Shanghai Jiao Tong University reporting a copper-catalyzed method for synthesizing chiral phosphates in #JACS.
This research represents a new tool for the synthesis of ProTide nucleoside analogues, providing an efficient route that can enhance the development of antiviral drugs in future studies.
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My evening lecture: Total synthesis of cylindrocyclophane A by Davies and Craig published in #Science and the stereoselective synthesis of protides by Shang published in #JACS
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My evening lecture: Total synthesis of cylindrocyclophane A by Davies and Craig published in #Science and the stereoselective synthesis of protides by Shang published in #JACS
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My evening lecture: Total synthesis of cylindrocyclophane A by Davies and Craig published in #Science and the stereoselective synthesis of protides by Shang published in #JACS